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Estimation of Carbon Abundances in Metal-Poor Stars. I. Application to the Strong G-Band Stars of Beers, Preston, and Shectman
We develop and test a method for the estimation of metallicities([Fe/H]) and carbon abundance ratios ([C/Fe]) for carbon-enhancedmetal-poor (CEMP) stars based on the application of artificial neuralnetworks, regressions, and synthesis models to medium-resolution (1-2Å) spectra and J-K colors. We calibrate this method by comparisonwith metallicities and carbon abundance determinations for 118 starswith available high-resolution analyses reported in the recentliterature. The neural network and regression approaches make use of apreviously defined set of line-strength indices quantifying the strengthof the Ca II K line and the CH G band, in conjunction with J-K colorsfrom the Two Micron All Sky Survey Point Source Catalog. The use ofnear-IR colors, as opposed to broadband B-V colors, is required becauseof the potentially large affect of strong molecular carbon bands onbluer color indices. We also explore the practicality of obtainingestimates of carbon abundances for metal-poor stars from the spectralinformation alone, i.e., without the additional information provided byphotometry, as many future samples of CEMP stars may lack such data. Wefind that although photometric information is required for theestimation of [Fe/H], it provides little improvement in our derivedestimates of [C/Fe], and hence, estimates of carbon-to-iron ratios basedsolely on line indices appear sufficiently accurate for most purposes.Although we find that the spectral synthesis approach yields the mostaccurate estimates of [C/Fe], in particular for the stars with thestrongest molecular bands, it is only marginally better than is obtainedfrom the line index approaches. Using these methods we are able toreproduce the previously measured [Fe/H] and [C/Fe] determinations withan accuracy of ~0.25 dex for stars in the metallicity interval-5.5<=[Fe/H]<=-1.0 and with 0.2<=(J-K)0<=0.8. Athigher metallicity, the Ca II K line begins to saturate, especially forthe cool stars in our program, and hence, this approach is not useful insome cases. As a first application, we estimate the abundances of [Fe/H]and [C/Fe] for the 56 stars identified as possibly carbon-rich, relativeto stars of similar metal abundance, in the sample of ``strong G-band''stars discussed by Beers, Preston, and Shectman.

Sulphur abundances in metal-poor stars
We investigate the debated "sulphur discrepancy" found among metal-poorstars of the Galactic halo with [Fe/H] < -2. This discrepancy stemsin part from the use of two different sets of sulphur lines, the veryweak triplet at 8694-95 Å and the stronger triplet lines at9212-9238 Å. For three representative cases of metal-poor dwarf,turnoff and subgiant stars, we argue that the abundances from theλλ8694-95 lines have been overestimated which has led to acontinually rising trend of [S/Fe] as metallicity decreases. Given thatthe near-IR region is subject to CCD fringing, these weak lines becomeexcessively difficult to measure accurately in the metallicity regime of[Fe/H] < -2. Based on homogeneously determined spectroscopic stellarparameters, we also present updated [S/Fe] ratios from theλλ9212-9238 lines which suggest a plateau-like behavioursimilar to that seen for other alpha elements.

Sulfur Abundances in Metal-Poor Stars Based on OAO-1.88m/HIDES Spectra
The LTE abundances of sulfur (S) of 21 metal-poor stars and one normalstar were explored in the metallicity range of -3 < [Fe/H] ≤ 0,based on the equivalent widths of the S I (1) 9212, 9237Å and S I(6) 8693, 9894Å lines measured on high-resolution spectra, whichwere observed by the OAO 1.88-m telescope equipped with HIDES. Our mainresults are: (1) The abundances derived from the S I (6) lines areconsistent with those from the S I (1) lines among our sample stars inthe range of [Fe/H] > -2 with an average difference of +0.03 ±0.05 dex, whereas a significant discrepancy is observed in the range of[Fe/H] ≤ -2. (2) The behavior of [S(6)/Fe], versus [Fe/H] of ourhalo sample stars exhibits a nearly flat trend with an average of +0.62± 0.09 dex in the range of -3 < [Fe/H] < -1.25, and shows adistribution around +0.29 dex in -1.25 ≤ [Fe/H] ≤ -0.7. Oursample stars with -1.25 ≤ [Fe/H] ≤ -0.5 follow an increasingtrend with decreasing [Fe/H]. The behavior of [S(1)/Fe] of our samplestars also shows essentially the same trend as [S(6)/Fe], though it isquantitatively different. (3) The S behavior in the range of -3 <[Fe/H] ≤ 0 inferred from the abundances of multiplets 6 and 1 arequalitatively consistent with each other, and may be represented by acombination of a nearly flat trend and a linearly increasing trend withdecreasing [Fe/H]. A transition of the trend is likely to occur at[Fe/H] ˜ -1.5 dex.

Subaru/HDS Abundances in Three Giant Stars in the Ursa Minor Dwarf Spheroidal Galaxy
With the HDS (High Dispersion Spectrograph) on the Subaru Telescope, weobtained high-resolution optical region spectra of three red giant stars(COS 4, COS 82, and COS 347) in the Ursa Minor dwarf spheroidal galaxy.The chemical abundances in these stars were analyzed for 26 elements,including α-, iron-peak, and neutron-capture elements. All threestars show low abundances of α-elements (Mg, Si, and Ca), and twostars (COS 82 and COS 347) show high abundances of Mn compared toGalactic halo stars of similar metallicity. One star (COS 4) has beenconfirmed to be very metal deficient ([Fe/H] = ‑2.7) and found toshow anomalously low abundances of Mn, Cu, and Ba. In another star, COS82 ([Fe/H] = ‑1.5), we have found a large excess of heavyneutron-capture elements with a general abundance pattern similar to thescaled solar system r-process abundance curve. These observationalresults are rather puzzling: low abundances of α-elements and highabundance of Mn seem to suggest a significant contribution of SNe Ia atlow metallicity, while there is no hint of an s-process (i.e., AGBstars) contribution, even at [Fe/H] = ‑1.5, suggesting a peculiarnucleosynthetic history of the UMi dSph galaxy.

Stellar Chemical Signatures and Hierarchical Galaxy Formation
To compare the chemistries of stars in the Milky Way dwarf spheroidal(dSph) satellite galaxies with stars in the Galaxy, we have compiled alarge sample of Galactic stellar abundances from the literature. Whenkinematic information is available, we have assigned the stars tostandard Galactic components through Bayesian classification based onGaussian velocity ellipsoids. As found in previous studies, the[α/Fe] ratios of most stars in the dSph galaxies are generallylower than similar metallicity Galactic stars in this extended sample.Our kinematically selected stars confirm this for the Galactic halo,thin-disk, and thick-disk components. There is marginal overlap in thelow [α/Fe] ratios between dSph stars and Galactic halo stars onextreme retrograde orbits (V<-420 km s-1), but this is notsupported by other element ratios. Other element ratios compared in thispaper include r- and s-process abundances, where we find a significantoffset in the [Y/Fe] ratios, which results in a large overabundance in[Ba/Y] in most dSph stars compared with Galactic stars. Thus, thechemical signatures of most of the dSph stars are distinct from thestars in each of the kinematic components of the Galaxy. This resultrules out continuous merging of low-mass galaxies similar to these dSphsatellites during the formation of the Galaxy. However, we do not ruleout very early merging of low-mass dwarf galaxies, since up to one-halfof the most metal-poor stars ([Fe/H]<=-1.8) have chemistries that arein fair agreement with Galactic halo stars. We also do not rule outmerging with higher mass galaxies, although we note that the LMC and theremnants of the Sgr dwarf galaxy are also chemically distinct from themajority of the Galactic halo stars. Formation of the Galaxy's thickdisk by heating of an old thin disk during a merger is also not ruledout; however, the Galaxy's thick disk itself cannot be comprised of theremnants from a low-mass (dSph) dwarf galaxy, nor of a high-mass dwarfgalaxy like the LMC or Sgr, because of differences in chemistry.The new and independent environments offered by the dSph galaxies alsoallow us to examine fundamental assumptions related to thenucleosynthesis of the elements. The metal-poor stars ([Fe/H]<=-1.8)in the dSph galaxies appear to have lower [Ca/Fe] and [Ti/Fe] than[Mg/Fe] ratios, unlike similar metallicity stars in the Galaxy.Predictions from the α-process (α-rich freeze-out) would beconsistent with this result if there have been a lack of hypernovae indSph galaxies. The α-process could also be responsible for thevery low Y abundances in the metal-poor stars in dSph's; since [La/Eu](and possibly [Ba/Eu]) are consistent with pure r-process results, thelow [Y/Eu] suggests a separate r-process site for this light(first-peak) r-process element. We also discuss SNe II rates and yieldsas other alternatives, however. In stars with higher metallicities([Fe/H]>=-1.8), contributions from the s-process are expected; [(Y,La, and Ba)/Eu] all rise as expected, and yet [Ba/Y] is still muchhigher in the dSph stars than similar metallicity Galactic stars. Thisresult is consistent with s-process contributions from lower metallicityAGB stars in dSph galaxies, and is in good agreement with the slowerchemical evolution expected in the low-mass dSph galaxies relative tothe Galaxy, such that the build-up of metals occurs over much longertimescales. Future investigations of nucleosynthetic constraints (aswell as galaxy formation and evolution) will require an examination ofmany stars within individual dwarf galaxies.Finally, the Na-Ni trend reported in 1997 by Nissen & Schuster isconfirmed in Galactic halo stars, but we discuss this in terms of thegeneral nucleosynthesis of neutron-rich elements. We do not confirm thatthe Na-Ni trend is related to the accretion of dSph galaxies in theGalactic halo.

Ca II K Emission-Line Asymmetries Among Red Giants
Measurements of the asymmetry of the K2 emission line of CaII have been made for a sample of bright field giants with B-V>1.15observed with the Cassegrain echelle spectrometer on the McDonaldObservatory 2.1 m telescope. The asymmetry of the Ca II K2line is quantified through measurement of a parameter V/R, which isdefined as the ratio between the maximum counts recorded in the violetand red components of the double-peaked emission profile. Red-maximumasymmetry (V/R<1.0) is found in our sample of 35 giants only amongstars with B-V>1.35, a trend that is still maintained (with oneexception) with the inclusion of an additional sample of giantspreviously observed by us with the same spectrograph. Althoughexceptional stars can be found in the literature, the data support anearlier finding by R. Stencel that among luminosity class III fieldgiants the occurrence of V/R<1.0 is generally restricted to effectivetemperatures cooler than 4320 K. This limit may coincide with the onsetof pulsation.

The Indo-US Library of Coudé Feed Stellar Spectra
We have obtained spectra for 1273 stars using the 0.9 m coudéfeed telescope at Kitt Peak National Observatory. This telescope feedsthe coudé spectrograph of the 2.1 m telescope. The spectra havebeen obtained with the no. 5 camera of the coudé spectrograph anda Loral 3K×1K CCD. Two gratings have been used to provide spectralcoverage from 3460 to 9464 Å, at a resolution of ~1 Å FWHMand at an original dispersion of 0.44 Å pixel-1. For885 stars we have complete spectra over the entire 3460 to 9464 Åwavelength region (neglecting small gaps of less than 50 Å), andpartial spectral coverage for the remaining stars. The 1273 stars havebeen selected to provide broad coverage of the atmospheric parametersTeff, logg, and [Fe/H], as well as spectral type. The goal ofthe project is to provide a comprehensive library of stellar spectra foruse in the automated classification of stellar and galaxy spectra and ingalaxy population synthesis. In this paper we discuss thecharacteristics of the spectral library, viz., details of theobservations, data reduction procedures, and selection of stars. We alsopresent a few illustrations of the quality and information available inthe spectra. The first version of the complete spectral library is nowpublicly available from the National Optical Astronomy Observatory(NOAO) via ftp and http.

Empirically Constrained Color-Temperature Relations. II. uvby
A new grid of theoretical color indices for the Strömgren uvbyphotometric system has been derived from MARCS model atmospheres and SSGsynthetic spectra for cool dwarf and giant stars having-3.0<=[Fe/H]<=+0.5 and 3000<=Teff<=8000 K. Atwarmer temperatures (i.e., 8000-2.0. To overcome thisproblem, the theoretical indices at intermediate and high metallicitieshave been corrected using a set of color calibrations based on fieldstars having well-determined distances from Hipparcos, accurateTeff estimates from the infrared flux method, andspectroscopic [Fe/H] values. In contrast with Paper I, star clustersplayed only a minor role in this analysis in that they provided asupplementary constraint on the color corrections for cool dwarf starswith Teff<=5500 K. They were mainly used to test thecolor-Teff relations and, encouragingly, isochrones thatemploy the transformations derived in this study are able to reproducethe observed CMDs (involving u-v, v-b, and b-y colors) for a number ofopen and globular clusters (including M67, the Hyades, and 47 Tuc)rather well. Moreover, our interpretations of such data are verysimilar, if not identical, with those given in Paper I from aconsideration of BV(RI)C observations for the sameclusters-which provides a compelling argument in support of thecolor-Teff relations that are reported in both studies. Inthe present investigation, we have also analyzed the observedStrömgren photometry for the classic Population II subdwarfs,compared our ``final'' (b-y)-Teff relationship with thosederived empirically in a number of recent studies and examined in somedetail the dependence of the m1 index on [Fe/H].Based, in part, on observations made with the Nordic Optical Telescope,operated jointly on the island of La Palma by Denmark, Finland, Iceland,Norway, and Sweden, in the Spanish Observatorio del Roque de losMuchachos of the Instituto de Astrofisica de Canarias.Based, in part, on observations obtained with the Danish 1.54 mtelescope at the European Southern Observatory, La Silla, Chile.

Oxygen Abundances in Metal-poor Stars
We present oxygen abundances derived from both the permitted andforbidden oxygen lines for 55 subgiants and giants with [Fe/H] valuesbetween -2.7 and solar with the goal of understanding the discrepancy inthe derived abundances. A first attempt, using Teff valuesfrom photometric calibrations and surface gravities from luminositiesobtained agreement between the indicators for turn-off stars, but thedisagreement was large for evolved stars. We find that the difference inthe oxygen abundances derived from the permitted and forbidden lines ismost strongly affected by Teff, and we derive a newTeff scale based on forcing the two sets of lines to give thesame oxygen abundances. These new parameters, however, do not agree withother observables, such as theoretical isochrones or Balmer-line profilebased Teff determinations. Our analysis finds thatone-dimensional, LTE analyses (with published non-LTE corrections forthe permitted lines) cannot fully resolve the disagreement in the twoindicators without adopting a temperature scale that is incompatiblewith other temperature indicators. We also find no evidence ofcircumstellar emission in the forbidden lines, removing such emission asa possible cause for the discrepancy.

Non-LTE Analysis of the Sodium Abundance of Metal-Poor Stars in the Galactic Disk and Halo
We performed an extensive non-LTE analysis of the neutral sodium linesof Na I 5683/5688, 5890/5896, 6154/6161, and 8183/8195 in disk/halostars of types F-K covering a wide metallicity range (-4 <≈[Fe/H] <≈ +0.4), using our own data as well as data collectedfrom the literature. For comparatively metal-rich disk stars (-1<≈ [Fe/H] <≈ +0.4) where the weaker 6154/6161 linesare the best abundance indicators, we confirmed [Na/Fe] ˜ 0 with an"upturn" (i.e., a shallow/broad dip around -0.5 <≈ [Fe/H]<≈ 0) as already reported in previous studies. For themetal-deficient halo stars, where the much stronger 5890/5896 or8183/8195 lines subject to considerable (negative) non-LTE correctionsamounting to 0.5 dex have to be used, our analysis suggests mildly"subsolar" [Na/Fe] values down to ˜ -0.4 (with a somewhat largescatter of ˜ ± 0.2 dex) on the average at the typical halometallicity of [Fe/H] ˜ -2, followed by a rise again to a near-solarratio of [Na/Fe] ˜ 0 at the very metal-poor regime [Fe/H] ˜ -3to -4. These results are discussed in comparison with the previousobservational studies along with the theoretical predictions from theavailable chemical evolution models.

Sodium Abundances in Stellar Atmospheres with Differing Metallicities
The non-LTE sodium abundances of 100 stars with metallicities-3<[Fe/H]<0.3 are determined using high-dispersion spectra withhigh signal-to-noise ratios. The sodium abundances [Na/Fe] obtained areclose to the solar abundance and display a smaller scatter than valuespublished previously. Giants (logg<3.8) with [Fe/H]<-1 do notdisplay overabundances of sodium, and their sodium abundances do notshow an anticorrelation with the oxygen abundance, in contrast toglobular-cluster giants. They likewise do not show sodium-abundancevariations with motion along the giant branch. No appreciable decreasein the sodium abundance was detected for dwarfs (logg>3.8) withmetallicities -2<[Fe/H]<-1. The observed relation between [Na/Fe]and [Fe/H] is in satisfactory agreement with the theoreticalcomputations of Samland, which take into account the metallicitydependence of the sodium yield and a number of other factors affectingthe distribution of elements in the Galaxy during the course of itsevolution.

Abundances of Cu and Zn in metal-poor stars: Clues for Galaxy evolution
We present new observations of copper and zinc abundances in 90metal-poor stars, belonging to the metallicity range -3<[Fe/H]<-0.5. The present study is based on high resolutionspectroscopic measurements collected at the Haute Provence Observatoire(R= 42 000, S/N>100). The trend of Cu and Zn abundances as a functionof the metallicity [Fe/H] is discussed and compared to that of otherheavy elements beyond iron. We also estimate spatial velocities andgalactic orbital parameters for our target stars in order to disentanglethe population of disk stars from that of halo stars using kinematiccriteria. In the absence of a firm a priori knowledge of thenucleosynthesis mechanisms controlling Cu and Zn production, and of therelative stellar sites, we derive constraints on these last from thetrend of the observed ratios [Cu/Fe] and [Zn/Fe] throughout the historyof the Galaxy, as well as from a few well established properties ofbasic nucleosynthesis processes in stars. We thus confirm that theproduction of Cu and Zn requires a number of different sources (neutroncaptures in massive stars, s-processing in low and intermediate massstars, explosive nucleosynthesis in various supernova types). We alsoattempt a ranking of the relative roles played by different productionmechanisms, and verify these hints through a simple estimate of thegalactic enrichment in Cu and Zn. In agreement with suggestionspresented earlier, we find evidence that type Ia Supernovae must play arelevant role, especially for the production of Cu. Based on the spectracollected with the 1.93-m telescope of Haute Provence Observatory.

The r-Process in the Early Galaxy
We report Sr, Pd, and Ag abundances for a sample of metal-poor fieldgiants and analyze a larger sample of Y, Zr, and Ba abundances. The[Y/Zr] and [Pd/Ag] abundance ratios are similar to those measured forthe r-process-rich stars CS 22892-052 and CS 31082-001. The [Pd/Ag]ratio is larger than predicted from the solar system r-processabundances. The constant [Y/Zr] and [Sr/Y] values in the field starsplace strong limits on the contributions of the weak s-process and themain s-process to the light neutron-capture elements. Stars in theglobular cluster M15 possess lower [Y/Zr] values than the field stars.There is a large dispersion in [Y/Ba]. Because the r-process isresponsible for the production of the heavy elements in the earlyGalaxy, these dispersions require varying light-to-heavy ratios inr-process yields.

HIPPARCOS age-metallicity relation of the solar neighbourhood disc stars
We derive age-metallicity relations (AMRs) and orbital parameters forthe 1658 solar neighbourhood stars to which accurate distances aremeasured by the HIPPARCOS satellite. The sample stars comprise 1382 thindisc stars, 229 thick disc stars, and 47 halo stars according to theirorbital parameters. We find a considerable scatter for thin disc AMRalong the one-zone Galactic chemical evolution (GCE) model. Orbits andmetallicities of thin disc stars show now clear relation each other. Thescatter along the AMR exists even if the stars with the same orbits areselected. We examine simple extension of one-zone GCE models whichaccount for inhomogeneity in the effective yield and inhomogeneous starformation rate in the Galaxy. Both extensions of the one-zone GCE modelcannot account for the scatter in age - [Fe/H] - [Ca/Fe] relationsimultaneously. We conclude, therefore, that the scatter along the thindisc AMR is an essential feature in the formation and evolution of theGalaxy. The AMR for thick disc stars shows that the star formationterminated 8 Gyr ago in the thick disc. As already reported by Grattonet al. (\cite{Gratton_et.al.2000}) and Prochaska et al.(\cite{Prochaska_et.al.2000}), thick disc stars are more Ca-rich thanthin disc stars with the same [Fe/H]. We find that thick disc stars showa vertical abundance gradient. These three facts, the AMR, verticalgradient, and [Ca/Fe]-[Fe/H] relation, support monolithic collapseand/or accretion of satellite dwarf galaxies as likely thick discformation scenarios. Tables 2 and 3 are only available in electronicform at the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5)or via http:/ /cdsweb.u-strasbg.fr/ cgi-bin/qcat?J/ A+A/394/927

Keck NIRSPEC Infrared OH Lines: Oxygen Abundances in Metal-poor Stars down to [Fe/H] = -2.9
Infrared OH lines at 1.5-1.7 μm in the H band were obtained with theNIRSPEC high-resolution spectrograph at the 10 m Keck Telescope for asample of seven metal-poor stars. Detailed analyses have been carriedout, based on optical high-resolution data obtained with the Fiber-fedExtended Range Optical Spectrograph at ESO. Stellar parameters werederived by adopting infrared flux method effective temperatures,trigonometric and/or evolutionary gravities, and metallicities from FeII lines. We obtain that the sample stars with metallicities[Fe/H]<-2.2 show a mean oxygen abundance [O/Fe]~0.54 for a solaroxygen abundance of ɛ(O)=8.87, or [O/Fe]~0.64 ifɛ(O)=8.77 is assumed. Observations carried out with the KeckTelescope within the Gemini-Keck agreement, and at the European SouthernObservatory.

Abundances of 30 Elements in 23 Metal-Poor Stars
We report the abundances of 30 elements in 23 metal-poor([Fe/H]<-1.7) giants. These are based on 7774 equivalent widths andspectral synthesis of 229 additional lines. Hyperfine splitting is takeninto account when appropriate. Our choice of model atmospheres has themost influence on the accuracy of our abundances. We consider the effectof different model atmospheres on our results. In addition to the randomerrors in Teff, logg, and microturbulent velocity, there areseveral sources of systematic error. These include using Teffdetermined from Fe I lines rather than colors, ignoring non-LTE effectson the Fe I/Fe II ionization balance, using models with solar[α/Fe] ratios, and using Kurucz models with overshooting. Ofthese, only the use of models with solar [α/Fe] ratios had anegligible effect. However, while the absolute abundances can change bygreater than 0.10 dex, the relative abundances, especially betweenclosely allied atoms such as the rare earth group, often show only small(less than 0.03 dex) changes. We found that some strong lines of Fe I,Mn I, and Cr I consistently gave lower abundances by ~0.2 dex, a numberlarger than the quoted errors in the gf-values. After considering amodel with depth-dependent microturbulent velocity and a model withhotter temperatures in the upper layers, we conclude that the latter dida better job of resolving the problem and agreeing with observationalevidence for the structure of stars. The error analysis includes theeffects of correlation of Teff, logg, and ξ errors, whichis crucial for certain element ratios, such as [Mg/Fe]. The abundancespresented here are being analyzed and discussed in a separate series ofpapers.

Abundances and Kinematics of Field Stars. II. Kinematics and Abundance Relationships
As an investigation of the origin of ``α-poor'' halo stars, weanalyze kinematic and abundance data for 73 intermediate-metallicitystars (-1>[Fe/H]>=-2) selected from Paper I of this series. We findevidence for a connection between the kinematics and the enhancement ofcertain element-to-iron ([X/Fe]) ratios in these stars. Statisticallysignificant correlations were found between [X/Fe] and galacticrest-frame velocities (vRF) for Na, Mg, Al, Si, Ca, and Ni,with marginally significant correlations existing for Ti and Y as well.We also find that the [X/Fe] ratios for these elements all correlatewith a similar level of significance with [Na/Fe]. Finally, we comparethe abundances of these halo stars against those of stars in nearbydwarf spheroidal (dSph) galaxies. We find significant differencesbetween the abundance ratios in the dSph stars and halo stars of similarmetallicity. From this result, it is unlikely that the halo stars in thesolar neighborhood, including even the ``α-poor'' stars, were oncemembers of disrupted dSph galaxies similar to those studied to date.

Three-dimensional Spectral Classification of Low-Metallicity Stars Using Artificial Neural Networks
We explore the application of artificial neural networks (ANNs) for theestimation of atmospheric parameters (Teff, logg, and [Fe/H])for Galactic F- and G-type stars. The ANNs are fed withmedium-resolution (Δλ~1-2 Å) non-flux-calibratedspectroscopic observations. From a sample of 279 stars with previoushigh-resolution determinations of metallicity and a set of (external)estimates of temperature and surface gravity, our ANNs are able topredict Teff with an accuracy ofσ(Teff)=135-150 K over the range4250<=Teff<=6500 K, logg with an accuracy ofσ(logg)=0.25-0.30 dex over the range 1.0<=logg<=5.0 dex, and[Fe/H] with an accuracy σ([Fe/H])=0.15-0.20 dex over the range-4.0<=[Fe/H]<=0.3. Such accuracies are competitive with theresults obtained by fine analysis of high-resolution spectra. It isnoteworthy that the ANNs are able to obtain these results withoutconsideration of photometric information for these stars. We have alsoexplored the impact of the signal-to-noise ratio (S/N) on the behaviorof ANNs and conclude that, when analyzed with ANNs trained on spectra ofcommensurate S/N, it is possible to extract physical parameter estimatesof similar accuracy with stellar spectra having S/N as low as 13. Takentogether, these results indicate that the ANN approach should be ofprimary importance for use in present and future large-scalespectroscopic surveys.

12C/13C in Metal-poor Field Halo Giants
We have estimated 12C/13C in 15 metal-poor(-2.4<=[Fe/H]<=-1.0) field halo giant stars from spectra of the13CO v=3-1 and v=2-0 band heads and surrounding12CO and 13CO R-branch lines. Our isotope ratiosare consistent with previous measurements for stars in our sample with12C/13C determined either from the infraredfirst-overtone bands of CO or from optical G-band spectra of CH and redsystem bands of CN. We have also compiled carbon isotope ratios from theliterature for a much larger sample of field and cluster red giantbranch (RGB) stars spanning a wide range of metallicities(-2.4<=[Fe/H]<=solar). Combining these data, we confirm thedecline of the isotope ratio as stars evolve up the RGB and we haveidentified a trend toward higher levels of mixing in more metal-poorstars. Standard RGB first dredge-up models do not predict the carbonisotope ratios that we observe in the more evolved (higher luminosity)metal-poor stars, but more recent models that account for other mixingmechanisms can explain these data; even for very metal-poor stars suchas those that we have observed in the Galactic halo.

Oxygen Abundances in Metal-poor Stars (-2.2<[Fe/H]<-1.2) from Infrared OH Lines
Infrared OH lines at 1.55-1.56 μm in the H band were obtained withthe Phoenix high-resolution spectrograph at the 2.1 m telescope of theKitt Peak National Observatory for a sample of 14 metal-poor stars.Detailed analyses of the sample stars have been carried out, derivingstellar parameters based on two methods: (a) spectroscopic parametersand (b) infrared flux method (IRFM) effective temperatures,trigonometric gravities, and metallicities from Fe II lines. The Fe Ilines present in the H-band region observed were well fitted by thestellar parameters within Δ[Fe/H]<=0.15 dex. The oxygenabundances were derived from fits of spectrum synthesis calculations tothe infrared OH lines. CO lines in the H and K bands were obtained for asubsample in order to determine their carbon abundances. Adopting thespectroscopic parameters, a mean oxygen-to-iron ratio of [O/Fe]~0.52 isobtained, whereas using the IRFM temperatures, Hipparcos gravities, and[Fe II/H], [O/Fe]~0.25 is found. A mean of the two methods gives a finalvalue of [O/Fe]~0.4 for the metallicity range -2.2<[Fe/H]<-1.2 ofthe sample metal-poor stars.

Th Ages for Metal-poor Stars
With a sample of 22 metal-poor stars, we demonstrate that theheavy-element abundance pattern (Z>=56) is the same as the r-processcontributions to the solar nebula. This bolsters the results of previousstudies that there is a universal r-process production pattern. We usethe abundance of thorium in five metal-poor stars, along with anestimate of the initial Th abundance based on the abundances of stabler-process elements, to measure their ages. We have four field red giantswith errors of 4.2 Gyr in their ages and one M92 giant with an error of5.6 Gyr, based on considering the sources of observational error only.We obtain an average age of 11.4 Gyr, which depends critically on theassumption of an initial Th/Eu production ratio of 0.496. If theuniverse is 15 Gyr old, then the (Th/Eu)0 should be 0.590, inagreement with some theoretical models of the r-process.

Analysis of neutron capture elements in metal-poor stars
We derived model atmosphere parameters (Teff, log g, [Fe/H],Vt) for 90 metal-deficient stars (-0.5<[Fe/H]<-3),using echelle spectra from the ELODIE library (Soubiran et al.\cite{soubet98}). These parameters were analyzed and compared withcurrent determinations by other authors. The study of the followingelements was carried out: Mg, Si, Ca, Sr, Y, Ba, La, Ce, Nd, and Eu. Therelative contributions of s- and r-processes were evaluated andinterpreted through theoretical computations of the chemical evolutionof the Galaxy. The chemical evolution models (Pagel &Tautvaišienė \cite{pagta95}; Timmes et al. \cite{timet95})depict quite well the behaviour of [Si/Fe], [Ca/Fe] with [Fe/H]. Thetrend of [Mg/Fe] compares more favourably with the computations of Pagel& Tautvaišienė (\cite{pagta95}) than those of Timmes etal. (\cite{timet95}). The runs of n-capture elements vs. metallicity aredescribed well both by the model of Pagel & Tautvaišienė(\cite{pagta95}, \cite{pagta97}) and by the model of Travaglio et al.(\cite{travet99}) at [Fe/H]>-1.5, when the matter of the Galaxy issufficiently homogeneous. The analysis of n-capture element abundancesconfirms the jump in [Ba/Fe] at [Fe/H]=-2.5. Some stars from our sampleat [Fe/H]<-2.0 show a large scatter of Sr, Ba, Y, Ce. This scatter isnot caused by the errors in the measurements, and may reflect theinhomogeneous nature of the prestellar medium at early stages ofgalactic evolution. The matching of [Ba/Fe], [Eu/Fe] vs. [Fe/H] with theinhomogeneous model by Travaglio et al. (\cite{travet01a}) suggests thatat [Fe/H]<-2.5, the essential contribution to the n-rich elementabundances derives from the r-process. The main sources of theseprocesses may be low mass SN II. The larger dispersion of s-processelement abundances with respect to alpha -rich elements may arise bothfrom the birth of metal-poor stars in globular clusters with followingdifferent evolutionary paths and (or) from differences in s-elementenrichment in Galaxy populations. Based on spectra collected at theObservatoire de Haute-Provence (OHP), France

On the stellar content of the open clusters Melotte 105, Hogg 15, Pismis 21 and Ruprecht 140
CCD observations in the B, V and I passbands have been used to generatecolour-magnitude diagrams reaching down to V ~ 19 mag for two slightlycharacterized (Melotte 105 and Hogg 15) and two almost unstudied (Pismis21 and Ruprecht 140) open clusters. The sample consists of about 1300stars observed in fields of about 4arcmin x4arcmin . Our analysis showsthat neither Pismis 21 nor Ruprecht 140 are genuine open clusters sinceno clear main sequences or other meaningful features can be seen intheir colour-magnitude diagrams. Melotte 105 and Hogg 15 are openclusters affected by E(B-V) = 0.42 +/- 0.03 and 0.95 +/- 0.05,respectively. Their distances to the Sun have been estimated as 2.2 +/-0.3 and 2.6 +/- 0.08 kpc, respectively, while the corresponding agesestimated from empirical isochrones fitted to the Main Sequence clustermembers are ~ 350 Myr and 300 Myr, respectively. The present data arenot consistent with the membership of the WN6 star HDE 311884 to Hogg15. Tables 2 to 5 are only available in electronic form at the CDS viaanonymous ftp to cdsarc.u-strasbg.fr (130.793.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/370/931

Neutron-Capture Elements in the Early Galaxy: Insights from a Large Sample of Metal-poor Giants
New abundances for neutron-capture (n-capture) elements in a largesample of metal-poor giants from the Bond survey are presented. Thespectra were acquired with the KPNO 4 m echelle and coudé feedspectrographs, and have been analyzed using LTE fine-analysis techniqueswith both line analysis and spectral synthesis. Abundances of eightn-capture elements (Sr, Y, Zr, Ba, La, Nd, Eu, and Dy) in 43 stars havebeen derived from blue (λλ4070-4710, R~20,000, S/Nratio~100-200) echelle spectra and red (λλ6100-6180,R~22,000, S/N ratio~100-200) coudé spectra, and the abundance ofBa only has been derived from the red spectra for an additional 27stars. Overall, the abundances show clear evidence for a largestar-to-star dispersion in the heavy element-to-iron ratios. Thiscondition must have arisen from individual nucleosynthetic events inrapidly evolving halo progenitors that injected newly manufacturedn-capture elements into an inhomogeneous early Galactic halointerstellar medium. The new data also confirm that at metallicities[Fe/H]<~-2.4, the abundance pattern of the heavy (Z>=56) n-captureelements in most giants is well-matched to a scaled solar systemr-process nucleosynthesis pattern. The onset of the main r-process canbe seen at [Fe/H]~-2.9 this onset is consistent with the suggestion thatlow mass Type II supernovae are responsible for the r-process.Contributions from the s-process can first be seen in some stars withmetallicities as low as [Fe/H]~-2.75 and are present in most stars withmetallicities [Fe/H]>-2.3. The appearance of s-process contributionsas metallicity increases presumably reflects the longer stellarevolutionary timescale of the (low-mass) s-process nucleosynthesissites. The lighter n-capture elements (Sr-Y-Zr) are enhanced relative tothe heavier r-process element abundances. Their production cannot beattributed solely to any combination of the solar system r- and mains-processes, but requires a mixture of material from the r-process andfrom an additional n-capture process that can operate at early Galactictime. This additional process could be the weak s-process in massive(~25 Msolar) stars, or perhaps a second r-process site, i.e.,different from the site that produces the heavier (Z>=56) n-captureelements.

Abundances and Kinematics of Field Halo and Disk Stars. I. Observational Data and Abundance Analysis
We describe observations and abundance analysis of a high-resolution,high signal-to-noise ratio survey of 168 stars, most of which aremetal-poor dwarfs. We follow a self-consistent LTE analysis technique todetermine the stellar parameters and abundances, and we estimate theeffects of random and systematic uncertainties on the resultingabundances. Element-to-iron ratios are derived for key α-, odd-Z,Fe-peak, and r- and s-process elements. Effects of non-LTE on theanalysis of Fe I lines are shown to be very small on average.Spectroscopically determined surface gravities are derived that arequite close to those obtained from Hipparcos parallaxes.

Photometric Variability in a Sample of 187 G and K Giants
We have used three automatic photoelectric telescopes to obtainphotometric observations of 187 G, K, and (a few) M0 field giants. Wefind low-amplitude photometric variability on timescales of days toweeks on both sides of the coronal dividing line (CDL) in a total of 81or 43% of the 187 giants. About one-third of the variables haveamplitudes greater than 0.01 mag in V. In our sample the percentage ofvariable giants is a minimum for late-G spectral classes and increasesfor earlier and later classes; all K5 and M0 giants are variable. Wealso obtained high-resolution, red wavelength spectroscopic observationsof 147 of the giants, which we used to determine spectralclassifications, vsini values, and radial velocities. We acquiredadditional high-resolution, blue wavelength spectra of 48 of the giants,which we used to determine chromospheric emission fluxes. We analyzedthe photometric and spectroscopic observations to identify the cause(s)of photometric variability in our sample of giants. We show that thelight variations in the vast majority of G and K giant variables cannotbe due to rotation. For giants on the cool side of the CDL, we find thatthe variability mechanism is radial pulsation. Thus, the variabilitymechanism operating in M giants extends into the K giants up to aboutspectral class K2. On the hot side of the CDL, the variability mechanismis most likely nonradial, g-mode pulsation.

Kinematics of Metal-poor Stars in the Galaxy. II. Proper Motions for a Large Nonkinematically Selected Sample
We present a revised catalog of 2106 Galactic stars, selected withoutkinematic bias and with available radial velocities, distance estimates,and metal abundances in the range -4.0<=[Fe/H]<=0.0. This updateof the 1995 Beers & Sommer-Larsen catalog includes newly derivedhomogeneous photometric distance estimates, revised radial velocitiesfor a number of stars with recently obtained high-resolution spectra,and refined metallicities for stars originally identified in the HKobjective-prism survey (which account for nearly half of the catalog)based on a recent recalibration. A subset of 1258 stars in this cataloghave available proper motions based on measurements obtained with theHipparcos astrometry satellite or taken from the updated AstrographicCatalogue (second epoch positions from either the Hubble Space TelescopeGuide Star Catalog or the Tycho Catalogue), the Yale/San Juan SouthernProper Motion Catalog 2.0, and the Lick Northern Proper Motion Catalog.Our present catalog includes 388 RR Lyrae variables (182 of which arenewly added), 38 variables of other types, and 1680 nonvariables, withdistances in the range 0.1 to 40 kpc.

Revised Strömgren metallicity calibration for red giants
A new calibration of the Strömgren (b-y),m_1 diagram in terms ofiron abundance of red giants is presented. This calibration is based ona homogeneous sample of giants in the globular clusters omega Centauri,M 22, and M 55 as well as field giants from the list of Anthony-Twarog& Twarog (\cite{anth98}). Towards high metallicities, the newcalibration is connected to a previous calibration by Grebel &Richtler (\cite{greb92}), which was unsatisfactory for iron abudanceslower than -1.0 dex. The revised calibration is valid for CN-weak/normalred giants in the abundance range of -2.0 <[Fe/H]< 0.0 dex, and acolor range of 0.5 < (b-y) < 1.1 mag. As shown for red giants inomega Centauri, CN-weak stars with Strömgren metallicities higherthan -1.0 dex cannot be distinguished in the (b-y),m_1 diagram fromstars with lower iron abundances but higher CN band strengths. Based ondata collected at the European Southern Observatory, La Silla, Chile

The effective temperature scale of giant stars (F0-K5). I. The effective temperature determination by means of the IRFM
We have applied the InfraRed Flux Method (IRFM) to a sample ofapproximately 500 giant stars in order to derive their effectivetemperatures with an internal mean accuracy of about 1.5% and a maximumuncertainty in the zero point of the order of 0.9%. For the applicationof the IRFM, we have used a homogeneous grid of theoretical modelatmosphere flux distributions developed by \cite[Kurucz (1993)]{K93}.The atmospheric parameters of the stars roughly cover the ranges: 3500 K<= T_eff <= 8000 K; -3.0 <= [Fe/H] <= +0.5; 0.5 <= log(g) <= 3.5. The monochromatic infrared fluxes at the continuum arebased on recent photometry with errors that satisfy the accuracyrequirements of the work. We have derived the bolometric correction ofgiant stars by using a new calibration which takes the effect ofmetallicity into account. Direct spectroscopic determinations ofmetallicity have been adopted where available, although estimates basedon photometric calibrations have been considered for some stars lackingspectroscopic ones. The adopted infrared absolute flux calibration,based on direct optical measurements of stellar angular diameters, putsthe effective temperatures determined in this work in the same scale asthose obtained by direct methods. We have derived up to fourtemperatures, TJ, TH, TK and T_{L'},for each star using the monochromatic fluxes at different infraredwavelengths in the photometric bands J, H, K and L'. They show goodconsistency over 4000 K, and there is no appreciable trend withwavelength, metallicity and/or temperature. We provide a detaileddescription of the steps followed for the application of the IRFM, aswell as the sources of error and their effect on final temperatures. Wealso provide a comparison of the results with previous work.

CH, CN, and NH Band Strengths of Metal-poor Cluster and Field Red Giants
The strengths of the CN, NH, and CH bands in the spectra of PopulationII red giants are discussed based on observations of a sample of bothglobular cluster and field giants. We confirm an anticorrelation betweenthe oxygen abundance and the CN indices and a correlation between the3883 Å CN band and the 3360 Å NH band strengths among giantsin the globular clusters M15 and M13. We find one M15 star (IV-38) witha strong 3883 Å CN band and detectable 4215 Å CN and 3360Å NH bands. Abundance analysis of M15 IV-38 reveals a comparablecarbon abundance to a comparison star that has much weaker CN bands. Onepossible reason for this may be that IV-38 is an insipid CH star thathas also undergone some deep mixing. Alternatively, the atmosphere ofIV-38 may have been extensively processed through the O-->N cycle ofhydrogen burning such that carbon has been affected by O-->Cconversion. By combining our data set with material from the literatureand high-quality B-V photometry, we find that the CN band strengthdifferences among the M5 red giants do not appear to broaden the giantbranch of that cluster within the photometric errors. Using the CN, CH,and NH bands, we are able to confirm that the metal-poor field giant HD135148 is a CH-strong star and has not undergone deep mixing.

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